Enhanced Photoluminescence Properties of Li/Al-doped YPO4:Eu Phosphors

نویسندگان

  • R. Balakrishnaiah
  • Dong Woo Kim
  • Soung Soo Yi
  • Sung Hoon Kim
  • Kiwan Jang
  • Ho Sueb Lee
  • Byung Kee Moon
  • Jung Hyun Jeong
چکیده

Different concentrations of Li/Al-doped YPO4:Eu0.05 phosphors have been prepared by the solid state reaction method and are characterized by X-ray diffraction, scanning electron microscopy, excitation and emission measurements. The dependence of various optical and morphological properties of the prepared materials on Li/Al concentration has been discussed in our present work. Incorporation of Li + /Al 3+ ions into the YPO4:Eu phosphors has greatly enhanced the crystallinity, particle size and hence the luminescence properties and the optimum concentration in case of both Li and Al dopants are found to be 10 mol %. The improvement in PL performance with Li/Al-doping may result from the improved crystallinity and from the enlarged grain sizes inducing lower scattering loss and distortion of symmetry. The results are discussed in comparison of results with similar reported works.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Enhancing Photovoltaic Performance Using Broadband Luminescent Down-Shifting by Combining Multiple Species of Eu-Doped Silicate Phosphors

This paper demonstrates the application of a broadband luminescent downshifting (LDS) layer with multiple species of europium (Eu)-doped silicate phosphors using spin-on film technique to enhance the photovoltaic efficiency of crystalline silicon solar cells. The surface morphology of the deposited layer was examined using a scanning electron microscope (SEM). The chemical composition of the Eu...

متن کامل

Pechini synthesis of lanthanide (Eu3+/Tb3+or Dy3+) ions activated BaGd2O4 nanostructured phosphors: an approach for tunable emissions.

Trivalent lanthanide (Eu(3+), Tb(3+) and Dy(3+)) ions activated tunable color emitting BaGd2O4 (BG) phosphors were synthesized by a facile Pechini-type sol-gel process. The X-ray diffraction pattern confirmed the orthorhombic phase after annealing at 1300 °C for 5 h. Morphological studies were performed based on the analysis of transmission electron microscopy images, which showed needle type n...

متن کامل

Blue Emission in Ce and Eu Activated Lithium Fluoro Borate Phosphors

Using a simple combustion process, rare earth doped novel compounds like fluorides LiBF4 and Li3BF6 can be prepared. Combustion synthesis furnishes a quick method for preparation of these phosphors. The prepared phosphors were characterized by the photoluminescence (PL) techniques. It is suggested that borofluoride based materials can be developed as low-cost phosphors. Formation of single phas...

متن کامل

The Effect of Annealing, Synthesis Temperature and Structure on Photoluminescence Properties of Eu-Doped ZnO Nanorods

In this study un-doped and Eu-doped ZnO nanorods and microrads were fabricated by Chemical Vapor Deposition (CVD) method. The effects of annealing, synthesis temperature and structure on structural and photoluminescence properties of Eu-doped ZnO samples were studied in detail. Prepared samples were characterized using X-Ray diffraction (XRD), scanning electron microscopy (SEM), particle size a...

متن کامل

New Insight into Phase Formation of MxMg2Al4+xSi5−xO18:Eu2+ Solid Solution Phosphors and Its Luminescence Properties

Here we reported the phase formation of MxMg2Al(4+x)Si(5-x)O18:Eu(2+) (M = K, Rb) solid solution phosphors, where M(+) ions were introduced into the void channels of Mg2Al4Si5O18 via Al(3+)/Si(4+) substitution to keep the charge balance. XRD results revealed that the as-prepared phosphors with different M(+) contents were iso-structural with Mg2Al4Si5O18 phase. The combined analysis of the Riet...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2010